This process involves the deposition of metallic layers onto the photovoltaic cells to alter their surface properties and improve their performance. Silicon electrodeposition offers an effective alternative to CVD for making silicon devices with substantially reduced processing costs so that solar photovoltaics can be cost competiti e with the typical cost for. Researchers at the Fraunhofer Institute for Solar Energy Systems (ISE) have developed two electroplating processes in which silver is replaced by copper. This is because rising raw material prices and a lack of availability, particularly of silver, are causing the production costs of photovoltaic. Electroplating, a widely-used industrial process that involves the coating of a surface with a thin layer of metal using an electric current, is paving new ways for enhancing the efficiency of photovoltaic cells. These modules combine 36 to 72 interconnected photovoltaic cells into a unified, weatherproof unit, serving as the essential. In different parts of the globe an industrially viable electroplating route using a sacrificial organic resist-mask (on a PVD metal-seed deposited on the transparent conductive oxide (TCO)) is under development and outstanding efficiencies around 25% were reported [2, 11].